Synthesis, Spectral and Antibacterial studies of some transition metal complexes with Schiff base derived from thiosemicarbazide and Phthalaldyde
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Schiff Base, Metal Complexes, Spectroscopic Study, Biological Activity
Abstract
Three transition metal Cr(III), Ni(II) and Cu(II) complexes of the Schiff base N,N՛-((1Z,1՛E)1,2-phenylenebis(methanelylidene)-bis(hydrazinecarbothioamide) have been synthesised and investigated using several techniques: physical characteristics, UV-Vis, mass spectra, molar conductivity, magnetic moment measurements, micro-analytical data (CHNS), 1HNMR and IR. The micro-analytical data indicate the formation of a 1:1[M:L] ratio. The molar conductance measurement showed that the [NiL(Cl)2] complex has a non-electrolytic nature. The molar conductance measurements of the complexes [Cr(H2L)(Cl)2 and [Cu(H2L)(H2O)2]Cl2 were electrolyte in nature and [Ni(H2O)Cl2] was non-electrolyte in nature. The infrared spectral data displayed the main coordination sites of N,N՛-((1Z,1՛E)1,2-phenylenebis (methane lylidene)-bis(hydrazinecarbothioamide) towards Cr(III), Ni(II) and Cu(II) ions. The electronic spectral results exhibited the presence of the electronic transitions in the free Schiff base and its complexes; the data suggested that the Cr(III), Ni(II) and Cu(II) complexes have an octahedral geometrical structure.
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References
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