Studying the Rheological Properties of Poly (Vinyl Pyrrolidone) in Chloroform Solutions
Article Sidebar
-
Chloroform, Flow Time, PVP, Viscosity
Abstract
Three molecular weights (25k, 44k and 700k) of Poly (vinyl-pyrrolidone), PVP solutions in chloroform, have been studied to conduct some of their rheological properties. In the temperature range of (25 - 45°C). Density and flow time parameters have been measured and used to calculate the viscosity parameter. The collected viscosity data suggests the ideal behaviour in the low concentrations of PVP solutions, due to the reduction of the interaction forces between molecules. However, the viscosity of higher concentrations is strongly affected by changing the molecular weight rather than the concentration itself. In addition, the density, flow time, and viscosity parameters of 700K are more influenced by the temperature change than the other two molecular weights.
Full text article
References
[1]-Teodorescu, M. and Bercea, M., (2015). Poly (vinylpyrrolidone)–a versatile polymer for biomedical and beyond medical applications.Polymer-Plastics Technology and Engineering,54(9), pp.923-943.
[2]-Park, I.K., Ihm, J.E., Park, Y.H., Choi, Y.J., Kim, S.I., Kim, W.J., Akaike, T. and Cho, C.S., (2003). Galactosylated chitosan (GC)-graft-poly (vinyl pyrrolidone)(PVP) as hepatocyte-targeting DNA carrier: Preparation and physicochemical characterization of GC-graft-PVP/DNA complex (1).Journal of controlled release,86(2-3), pp.349-359.
[3]-Raghunath,K., Rao, K.P., Nagarajan, B. and Joseph, K.T., (1985). Grafting of poly (vinyl pyrrolidone) onto gelatin and its application as synthetic plasma expander.European polymer journal,21(2), pp.195-199.
[4]-Menshikova, A.Y., Evseeva, T.G., Skurkis, Y.O., Tennikova, T.B. and Ivanchev, S.S., (2005). Monodisperse carboxylated polystyrene particles: synthesis, electrokinetic andadsorptive properties.Polymer,46(4), pp.1417-1425.
[5]-Wang, D., Dimonie, V.L., Sudol, E.D. and El‐Aasser, M.S., (2002). Effect of PVP in dispersion and seeded dispersion polymerizations.Journal of applied polymer science,84(14), pp.2721-2732.
[6]-Yan, N., Zhang, J.G., Tong, Y., Yao, S., Xiao, C., Li, Z. and Kou, Y., (2009). Solubility adjustable nanoparticles stabilized by a novel PVP based family: synthesis, characterization and catalytic properties.Chemical communications, (29), pp.4423-4425.
[7]-Sethia, S. and Squillante, E., (2004). Solid dispersion of carbamazepine in PVP K30 by conventional solvent evaporation and supercritical methods.International journal of pharmaceutics,272(1-2), pp.1-10.
[8]-Hickner, M.A., (2010). Ion-containing polymers: new energy & clean water.Materials Today,13(5), pp.34-41.
[9]-Hickner, M.A., (2012). Water‐mediated transport in ion‐containing polymers. Journal of Polymer Science Part B: Polymer Physics,50(1), pp.9-20.
[10]-Takada, H. and Matsubayashi, K., (2010).Method of producing pvp/fullerene complex and aqueous solution thereof. U.S. Patent Application 11/919,218.
[11]-Paudel, A. and Van den Mooter, G., (2012). Influence of solvent composition on the miscibility and physical stability of naproxen/PVP K 25 solid dispersions prepared by cosolvent spray-drying.Pharmaceutical research,29(1), pp.251-270.
[12]-Kabiri, K., Azizi, A., ZOHURIAAN, M.M.J., BAGHERI, M.G., Bouhendi, H. and Jamshidi, A.,. Super-alcogels based on 2-acrylamido-2-methylpropane sulphonic acid and poly (ethylene glycol) macromer. 2011
[13]-Ozawa, Y., Koyama, I. and Shimano, K., Taisho Pharmaceutical Co Ltd, (1991).Method of producing fine coated pharmaceutical preparation. U.S. Patent 5,017,383.
[14]-W. Billmeyer, T.R. "TextBook of polymer science", second Edition, by john Wiley&Sons. Inc.(1962).
[15]-W.Wilson, R.J.new comb, A.R.Denaru, R.M.Rickett, experiments in physical Chemistry,Program Press. 1962
[16]-Subramanian, R. and Natarajan, P., 1984. Interaction between poly (N‐vinylpyrrolidone) and poly (acrylic acid) s: influence of hydrogen and cupric ions on the adduct formation.Journal of Polymer Science: Polymer Chemistry Edition,22(2), pp.437-451.
[17]-Lugão, A.B., Rogero, S.O. and Malmonge, S.M., 2002. Rheological behaviour of irradiated wound dressing poly (vinyl pyrrolidone) hydrogels.Radiation Physics and Chemistry,63(3-6), pp.543-546.
[18]-Tan, Y.T., Peh, K.K. and Al-Hanbali, O., (2000). Effect of Carbopol and polyvinylpyrrolidone on the mechanical, rheological, and release properties of bioadhesive polyethylene glycol gels.AAPS PharmSciTech,1(3), pp.69-78.
[19]-Yang, H., Yan, Y., Zhu, P., Li, H., Zhu, Q. and Fan, C., 2005. Studies on the viscosity behavior of polymer solutions at low concentrations.European polymer journal,41(2), pp.329-340.
Authors
Copyright (c) 2020 Journal of Pure & Applied Sciences
This work is licensed under a Creative Commons Attribution 4.0 International License.
In a brief statement, the rights relate to the publication and distribution of research published in the journal of the University of Sebha where authors who have published their articles in the journal of the university of Sebha should how they can use or distribute their articles. They reserve all their rights to the published works, such as (but not limited to) the following rights:
- Copyright and other property rights related to the article, such as patent rights.
- Research published in the journal of the University of Sebha and used in its future works, including lectures and books, the right to reproduce articles for their own purposes, and the right to self-archive their articles.
- The right to enter a separate article, or for a non-exclusive distribution of their article with an acknowledgment of its initial publication in the journal of Sebha University.
Privacy Statement The names and e-mail addresses entered on the Sabha University Journal site will be used for the aforementioned purposes only and for which they were used.