The Inhibition of Mild Steel Corrosion by Sulphur Containing Organic Compound

Mohammed Sulimana (1) , Mohammed Almadanib (2) , Elfitouri Ahmied (3)
(1) Petroleum Department, Sabha University, Libya, Libya,
(2) Materials Department, Sabha University, Libya, Libya,
(3) Petroleum Department, Sirte University, Libya, Libya

Abstract

The inhibition of mild steel corrosion in "2.0 M sulphuric acid" solution by a Sulphur containing organic compound namely " Methyl Carbazodithoate " has been studied at temperature 30 ? by weight loss technique. Adsorption isotherms were tested for their relevance to describe the adsorption behaviour of methyl carbazodithoate. The experimental results show that the test inhibitor has a promising inhibitory action against corrosion of low carbon  steel in  the  medium  investigated. The inhibition efficiency was found to increase with a corresponding  increase in the concentration of the  inhibitor. The adsorption mechanism of methyl carbazodithoate inhibition is also proposed. The lower adsorption of sulphate ions on the carbon steel metal surface permits more space for the adsorption of inhibitor molecules and enhances inhibition of corrosion. Finally, the obtained results in this work indicates that the sulphur-containing inhibitor compound namely; "methyl carbazodithoate" compound is an effective inhibitor for corrosion inhibition of carbon steel in sulphuric acid solution.

Full text article

Generated from XML file

References

[1]-Eghbali F., Moayed M.H., Davoodi A., Ebrahimi N., Corros. Sci. 53 (2011) 513.

[2]-Fouda A.S., Ellithy A.S., Corros. Sci. 51(2009) 868.

[3]-Ramesh, S., Rajeswari, S. and Mathumitha, S. (2003). Materials Letters, 57, 4547.

[4]-Vasanth, K.L. NACE. National Association of Corrosion Engineers, Paper# 233, Corrosion 96.

[5]-Khaled, K.F. (2003). Electrochemical Acta, 48,2493.

[6]-Benabdellah M, Touzani R, Aouita A, Damali A, El-Kadiri S, Hamoudi B. Inhibitive action of some bipyrazole compounds on the corrosion of steel in 1 M HCl Part I: Electrochemical study. Mater.chem. Phys2007 ;105: 373-379.

[7]-Yildirim A, Cetin M. Synthesis and evaluation of new long alkyl side chain acetamide, is oxazolidine and isooxazoline derivatives as corrosion inhibitors. Crosscut 2008; 50: 155-165.

[8]-Obot IB, Obi-Egbeda NO, Fluconazole as an inhibitor for aluminum corrosion in 0.1 M Challacolloites and Surfaces: Colloids Surf. of Physicochemist. Eng. Aspects 2008; 330 :207-212.

[9]-Khaled KF, Al-Qahtani MM. The inhibitive effect of some tetrazole derivatives towards Al corrosion in acid solution: Chemical, electrochemical and theoretical studies, Mater.Chem. Phys 2009 ;113 :150 -158.

[10]-Ma H, Song T, Sun H, Li X. Experimental and theoretical elucidation on the inhibition mechanism of 1-methyl-5-mercapto-1,2,3,4-tetrazole self-assembled films on corrosion of iron in 0.5 M H2SO4Solutions. Thin Solid films 2008; 516:1020-1024.

[11]-Ju H, Kai ZP, Li Y. The Inhibitive effect of Ethanolamine on corrosion behavior of Aluminum in NaCl Solution Saturated with CO2. Corro's. Sci 2008; 50 :865-871.

[12]-M.E. Dietz, Low Impact Development Practices: A review of Current ResearchAndRecommendationfor Future Directions, Water, Air and Soil Pollution,186, 2007, pp. 351-363.

[13]-Y. Mei, X. H. Yang, R. Jiang, C. L. Dia, X. Jhang, Phosphorus isothermal adsorption characteristics of mulch of bioretention, Thermal Science, Vol. 16, No. 5, 2012, pp. 1358-1361.

[14]-S. Zhong-liang, L. Fu-Mei, Y. Shu-Hua, Adsorptive removal of phosphate fromAqueoussolutions using activated carbon loaded with Fe (III) oxide, New Carbon Materials, 26(4),2011, pp. 299–306 .

[15]-A.O. Dada, A.P. Olalekan, A.M. Olatunya, O. DADA, Langmuir, Freundlich, Temkin and Dubinin–Radosevich Isotherms Studies of Equilibrium Sorption of Zn2+ Unto Phosphoric Acid Modified Rice Husk, IOS Journal of Applied Chemistry (IOSR-JAC), Volume 3, 2012, pp.38-45, 72 GheorgheNechifor, Daniela Pascu, Mihaela Pascu, GinaTraistaru, Paul Constantin Albu.

[16]-B.H. Hameed, D.K. Mahmoud, A.L. Ahmad, Equilibrium modeling and kinetic student adsorption of basic dye by a low-cost adsorbent: Coconut (Cocos nucifera) bunch waste, Journal of Hazardous Materials, 158, 2008, pp. 65–772.[17]-C. Thevar's and Somlyay, Removal of Malachite Green from Aqueous Solution by Activated Carbon Developed from Cocoa (Theobroma Cacao) Shell -A Kinetic and Equilibrium Studies, E-Journal of Chemistry, 8(S1), 2011, pp.363-371.

[18]-Furstenau D.W. The adsorption of surfactants at solid water interfaces in: Hair ML, editor. The chemistry of insurances, (New York. 1971) 143.

[19]-Muralidharan, S and Iyer S V K, Electrochemist Soc, 142 (1995) 1478.

[20]-A.K. Singh, M.A. Quraishi, Corro's. Sci. 52 (2010) 1529.

[21]-Muralidharan, S and Iyer S V K, J Electracies, 142 (1995) 1478.

Authors

Mohammed Sulimana
Mohammed Almadanib
Elfitouri Ahmied
Sulimana, M. ., Almadanib, . M. ., & Ahmied, E. . (2019). The Inhibition of Mild Steel Corrosion by Sulphur Containing Organic Compound. Journal of Pure & Applied Sciences , 18(2), 59-63. https://doi.org/10.51984/jopas.v18i2.337

Article Details

How to Cite

Sulimana, M. ., Almadanib, . M. ., & Ahmied, E. . (2019). The Inhibition of Mild Steel Corrosion by Sulphur Containing Organic Compound. Journal of Pure & Applied Sciences , 18(2), 59-63. https://doi.org/10.51984/jopas.v18i2.337

Similar Articles

You may also start an advanced similarity search for this article.

No Related Submission Found