تحضير معقدات Cr(III), Mn(II). Ni(II), Cu(II) مع مرتبط 1-((2E,3E)-3-(هيدروكسي إمينو) بيوتان-2-إيل دين) يوريا
الملخص
الملخص تم تحضير مرتبط قاعدة شيف من تكثيف داي اسيتايل مونوكسايم مع اليوريا وتمت دراسته بواسطة التقنيات مثل التحليل العنصري والأشعة فوق بنفسجية والأشعة تحت الحمراء والرنين النووي المغناطيسي ومطياف الكتلة, وحضر منها متراكبات لقواعد شيف بتكثيفها مع أيونات Mn(II), Ni(II), Cu(II) ,Cr(III). وتم تحديد الاشكال الفراغية للمتراكبات بواسطة الطرق الطيفية والمغناطيسية, وإقترحت جميع المتراكبات ثمانية السطوح.
النص الكامل
المراجع
[1]-Kumar, N., Sharma, P., Pareek, A., & AVGS, P. (2013). International Journal of Chemical and Pharmaceutical Sciences.Synthesis,4(1),1.
[2]-Abirami, M., Nadaraj, V. (2014). Synthesis of schiff base under solvent-free condition: as a green approach.International Journal of ChemTech Research,6(4), 2534-2538.
[3]-Ibrahim, M. N., & Sharif, S. E. (2007). Synthesis, characterization and use of Schiff bases as fluorimetric analytical reagents.Journal of Chemistry,4(4), 531-535.
[4]-Hussain, Z., Yousif, E., Ahmed, A., & Altaie, A. (2014). Synthesis and characterization of Schiff's bases of sulfamethoxazole.Organic and medicinal chemistry letters,4(1), 1.
[5]-Munde, A. S., Jagdale, A. N., Jadhav, S. M., & Chondhekar, T. K. (2010). Synthesis, characterization and thermal study of some transition metal complexes of an asymmetrical tetradentate Schiff base ligand.Journal of the Serbian Chemical Society,75(3),349-359.
[6]-Khalil, Z. H., Abdel-Hafez, A. A., Yanni, A. S., & Moharam, A. M. (1988). Studies on metal chelates of 8-hydroxy-5-quinolyl ketone oxime, O-carbamoyl and O-thiocarbamoyl derivatives as bactericides.Bulletin of the Chemical Society of Japan,61(11), 4143-4146.
[7]-Endres, H., A. Bongart, D. Nothe, I. Hennig, D. Schweitzer, H. Schafer, H.W. Heiberg, and S. Flandrois, A Novel Molecular Metal:(Oxamide oximato)(Oxamide oxime) nickel (II). Tetracyanoquinodimethanide,[Ni (oaoH)(oaoH2)] tcnq, and Physical Properties of its Semiconducting Pt Analogue. Zeitschrift für Naturforschung B, 1985. 40(4): p. 489-495.
[8]-Tschugaeff L. Z. Anorg. Chem. 1905; 46: 144.
[9]-Radhakrishnan, T., P. Sreekumari Nair, G. Kolawole, N. Revaprasadu, G. Hawkes, M. Motevalli, E. Bento, and P. O'Brien, Reaction of o‐phenylenediamine with diacetyl monoxime: characterisation of the product by solid‐state 13C and 15N MAS NMR. Magnetic Resonance in Chemistry, 2007. 45(1): p. 59-64.
[10]-Mahalakshmi, N., & Rajavel, R. (2011). Synthesis, spectroscopic characterization, DNA cleavage and antimicrobial activity of binuclear copper (II), nickel (II) and oxovanadium (IV) Schiff base complexes.Asian J Biochem. Phermaceutical Res,1, 525-543.
[11]-Khan, F., Khan, S., & Athar, A. (2015). Synthesis, Spectral Characterization and Antibacterial Study of a Schiff Base Metal Complexes Derived from N-[(E)-(5-Chloro-2-Hydroxyphenyl) Methylidene]-4-Nitrobenzenesulfonamide.
[12]-Sobola, A. O., Watkins, G. M., & Van Brecht, B. (2014). Synthesis, characterization and antimicrobial activity of copper (II) complexes of some ortho-substituted aniline Schiff bases; crystal structure of bis (2-methoxy-6-imino) methylphenol copper (II) complex.South African Journal of Chemistry,67(1), 45-51.
[13]-Akbolat, N3, Yıldız, A3, Temel, H3, Ilhan, S3, & Gul, G. (2012). Antifungal studies of some metal complexes with Schiff base ligands.DUFED,1(1), 15-22.
[14]-Fareed, G., Versiani, M. A., Afza, N., Fareed, N., Iqbal, L., & Lateef, M. (2013). Structure activity relationship: Antioxidant potential of some novel Schiff bases containing benzophenone moiety.Int. J. Curr. Pharm. Res,5, 61-64.
[15]-Kumar, S., Dhar, D. N., & Saxena, P. (2009). Applications of metal complexes of Schiff bases a review. Journal of Scientific and Industrial Research, 68(3), 181-187.
[16]-Derebe, M. G., Raju, V. J. T., & Retta, N. (2002). Synthesis and characterization of some metal complexes of a Schiff base derived from ninhydrin and α, L-alanine.Bulletin of the Chemical Society of Ethiopia,16(1), 53-64.
[17]-Khalifa, K. M., Hamil, A. M., qasem, A., & Abdulsalam, A. (2010). Synthesis and Characterization of Some Ni (II) and Cu (II) Complexes with 2-[(4-Aminophenyl) imino]-1, 2-diphenyl-1-ethanone.Journal of Chemistry,7(1), 49-54.
[18]-Hamil, A. M., Abdelkarem, M., & El-ajaily, M. H. M. (2012). Synthesis of a New Schiff Base: 2-[2-(E)-(2-hydroxyphenyl)-ethylidene] aminoethyl)ethanimidoyl]phen.Synthesis,4(2), 682-685.
[19]-Boghaei, D. M., & Lashanizadegan, M. (2000). Template synthesis, characterization of highly unsymmetrical tetradentate Schiff base complexes of nickel (II) and copper (II).
[20]-Anuradha, K., & Rajavel, R. (2012). Antibacterial Activity of Macrocyclic Complexes of Cu (II), Ni (II) and VO (II) Derived from o-Aminobenzaldehyde.Journal of Chemistry,9(1), 481-486.
[21]-Deshmukh, P. S., Kaul, A. R., & Bhojane, J. N. (2010). Synthesis, Characterization and Thermogravimetric Studies of Some Metal Complexes with N2O2Schiff Base Ligand.World Applied Sciences Journal,9(11), 1301-1305.
[22]-Singh metal complexes of bis (pyridine-2-carbo) hydrazide and their antimicrobial studies.Journal o, N. P., & Singh, J. (2012). Magnetic and spectroscopic studies of the synthesized f Chemistry,9(4), 1835-1842.
[23]-Raman, N., Ravichandran, S., & Thangaraja, C. (2004). Copper (II), cobalt (II), nickel (II) and zinc (II) complexes of Schiff base derived from benzil-2, 4-dinitrophenylhydrazone with aniline.Journal of Chemical Sciences,116(4), 215-219.
[24]-Anupama, B., Padmaja, M., & Kumari, C. G. (2012). Synthesis, characterization, biological activity and DNA binding studies of metal complexes with 4-Aminoantipyrine Schiff base ligand.Journal of Chemistry,9(1), 389-400.
[25]-Soliman, M. H., & Mohamed, G. G. (2013). Cr (III), Mn (II), Fe (III), Co (II), Ni (II), Cu (II) and Zn (II) new complexes of 5-aminosalicylic acid: spectroscopic, thermal characterization and biological activity studies.Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy,107, 8-15.
[26]-Mittal, P., Joshi, S., Panwar, V., & Uma, V. (2009). Biologically active Co (II), Ni (II), Cu (II) and Mn (II) complexes of Schiff bases derived from vinyl aniline and heterocyclic aldehydes.Int. J. ChemTech Res,1, 225-232.
[27]-Rahangdale, M., G. Pethe, A. Yaul, and A. Aswar, Synthesis, Spectral Characterization and Antimicrobial Studies of some Transition Metal Complexes with ONNO-donor tetradentate ligand. Research Journal of Pharmaceutical, Biological and Chemical Science.
[28]-Raman, N., Ravichandran, S., & Thangaraja, C. (2004). Copper (II), cobalt (II), nickel (II) and zinc (II) complexes of Schiff base derived from benzil-2, 4-dinitrophenylhydrazone with aniline.Journal of Chemical Sciences,116(4), 215-219.
[29]-Ramadthan, E. M. (2013) , Synthesis and Characterization of New Some First Transition Metals Complexes of Schiff Base N,N'-bis[2-Methylenethio phene]-1,2-phenylenediimine. Iraqi National Journal of Chemistry, 50,154-166.
[30]-Çakır, Ü3, Temel, H3, İhan, S3, & Uğraş, H3 İ3 (2003). Spectroscopic and Conductance Studies of New Transition Metal Complexes with a Schiff Base Derived from 4‐Methoxybenzaldehyde and 1, 2‐bis (p‐Aminophenoxy) ethane.Spectroscopy letters,36(5-6), 429-440.
[31]-Annapoorani, S., & Krishnan, C. N. (2011). Studies on some Trinuclear Schiff base complexes.Int. J. Chem Tech Res,3, 1962-1968.
[32]-Baiu, S. H., El-Ajaily, M. M., & El-Barasi, N. M. (2009). Antibacterial activity of Schiff Base chelates of divalent metal ions.Asian Journal of Chemistry,21(1), 5. [33]-Mounika, K., Pragathi, A., & Gyanakumari, C. (2010). Synthesis characterization and biological activity of a Schiff base derived from 3-ethoxy salicylaldehyde and 2-amino benzoic acid and its transition metal complexes.Journal of Scientific Research,2(3), 513.
[34]-MOHAMED, G. G., Omar, M. M., & Hindy, A. M. (2006). Metal complexes of Schiff bases: preparation, characterization, and biological activity.Turkish Journal of Chemistry,30(3), 361-382.
[35]-Raman, N.,Raja, Y. P., & Kulandaisamy, A. (2001). Synthesis and characterisation of Cu (II), Ni (II), Mn (II), Zn (II) and VO (II) Schiff base complexes derived fromo-phenylenediamine and acetoacetanilide.Journal of Chemical Sciences,113(3), 183-189.
[36]-El-Ajaily, M. M., & El-Saied, F. M. (2007). Synthesis and Characterization of Urea Schiff Base Chelates of Cr (III), Cr (VI), TiO (IV) and Pb (II).Asian Journal of Chemistry,19(6), 4433.
[37]-Mishra, D. K., & Mishra, A. P. (2011). Synthesis structural characterization and biological significance of some novel Schiff base complexes with Co (II), Ni (II) and Cu (II).Int. J. Pharm.
[38]-Emara, A. A., & Adly, O. M. (2007). Synthesis and spectroscopic studies of new binuclear transition metal complexes of Schiff bases derived from 4, 6-diacetylresorcinol.TransitionMetal Chemistry,32(7), 889-901.
المؤلفون

هذا العمل مرخص بموجب Creative Commons Attribution 4.0 International License.
في بيان موجز، تتعلق الحقوق بنشر وتوزيع البحوث المنشورة في مجلة جامعة سبها حيث يجب على المؤلفين الذين نشروا مقالاتهم في مجلة جامعة سبها كيف يمكن استخدامها أو توزيع مقالاتهم. ويحتفظون بجميع حقوقهم في المصنفات المنشورة، مثل (على سبيل المثال لا الحصر) الحقوق التالية:
- حقوق الطبع والنشر وحقوق الملكية الأخرى المتعلقة بالمقال المقدم، مثل حقوق براءات الاختراع.
- بحث منشور في مجلة جامعة سبها ويستخدم في الأعمال المستقبلية الخاصة به، بما في ذلك المحاضرات والكتب، والحق في إعادة إنتاج المقالات لأغراضها الخاصة، والحق في الأرشفة الذاتية لمقالاتهم.
- الحق في الدخول في مقال منفصل، أو للتوزيع غير الحصري لمقالهم مع إقرار بنشره الأولي في مجلة جامعة سبها.
- بيان الخصوصية سيتم استخدام الأسماء وعناوين البريد الإلكتروني التي تم إدخالها في موقع مجلة جامعة سبها للأغراض المذكورة فقط والتي استخدمت من أجلها.